Multiferroic materials

Figure 1: One of the underlying principles of the magnetoelectric effect. Applying a magnetic field changes the magnetic structure, and the crystal lattice responds by displacing ions, in order to minimize the total exchange plus lattice energy. There are many possible underlying mechanisms, all involving the electrons responsible for the magnetic moment. 

In the MAGNET section, one of the main foci is research into multiferroic and magnetoelectric materials. In these materials, electric polarization and magnetic order either co-exist or are directly coupled, enabling electrical control of magnetization or control of electric polarization via application of a magnetic field (see Figure 1). This mechanism may find future use in complex next-generation information technology, enabling logic and storage devices with low power consumption or as a control handle in spintronics devices.


Pulse field neutron diffraction setup
Figure 2: Pulsed field neutron diffraction setup, from [1]. A polychromatic neutron beams enters the magnetic solenoid, and probes a set of Bragg reflections along a certain momentum transfer direction. The delay of the pulse is tuned to the pulsed neutron beam in order to probe the desired magnetic Bragg reflection

At MAGNET, we focus on the fundamental science of understanding these complex materials. Employing neutron and x-ray diffraction techniques, we investigate the interplay of complex magnetic structures and the atomic displacement of ions in the crystal lattice. Using neutron spectroscopy, we investigate the magnetic couplings giving rise to magnetic order, and the exotic magnetoelastic excitations resulting from the spin-lattice coupling.

In order to study the many realizations of the magnetoelectric effect, we often apply magnetic and electrical fields to our samples, often at temperatures below 5 K. In a recent study, we employed pulsed magnetic fields up to 35 T in order to observe a reorientation of magnetic moments. Due to the magnetoelectric effect, the electric polarization flipped, along with the magnetic structure. The pulsed field-neutron diffraction setup is shown in Figure 2. 

Rasmus Toft-Pedersen
Figure 3: (Left) Magnetic (x, T) phase diagram of LiNi1-xFexPO4. (Right) Magnetoelectric coupling in LiNi0.8xFe0.2PO4. as a function of temperature, showing an order of magnitude enhancement compared to LiNiPO4 and LiFePO4. Figures from [2].